A new palladium catalyzed synthesis of ,-2,3-diarylsubstituted bicyclo[2.2.1]heptanes or bicyclo [2.2.1] hept-2-enes

Autor: Gian Paolo Chiusoli, Marta Catellani, Stefano Concari
Rok vydání: 1989
Předmět:
Zdroj: Tetrahedron. 45:5263-5268
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)81100-5
Popis: The title bicycloheptanes or bicycloheptenes, containing a phenyl group and an aryl group in 2,3 positions, are obtained by oxidative addition of aryl bromides to palladium(0), followed by double bond insertion and coupling with a phenyl group of tetraphenyl borate anion.
Databáze: OpenAIRE