| Autor: | Gunnar Westin, Mikael Kritikos, Marat Moustiakimov |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry Infrared spectroscopy General Chemistry Polymer Crystal structure Condensed Matter Physics Toluene Electronic Optical and Magnetic Materials Ion Biomaterials Hexane chemistry.chemical_compound Ultraviolet visible spectroscopy chemistry Polymer chemistry Alkoxide Materials Chemistry Ceramics and Composites |
| Zdroj: | Journal of Sol-Gel Science and Technology. 26:115-118 |
| ISSN: | 0928-0707 |
| DOI: | 10.1023/a:1020753805599 |
| Popis: | A new chloro-oxo-alkoxide, Sr2Er2OCl(OPr i )7(HOPr i )4 has been prepared by reacting 4ErCl3 with 5Sr dissolved in toluene:HOPr i . The structure, determined by single-crystal X-ray techniques, is built from two polymer strands, each formed by repeating two molecular Sr2Er2O(OPr i )7(HOPr i )4 complexes, inter-tied by a chloro atom. The four independent, but very similar complexes contain two Er and two Sr ions, all binding to a central oxo ion. The great similarity of the FT-IR and UV-vis-NIR spectra of the solid and the hexane/toluene/2-propanol solutions shows that the molecular complexes have similar complex structures in the solid state and in solution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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