Improved polyaromatic benzoin photoremovable protecting groups

Autor:	Neil R. Branda, Carl-Johan Carling, Laura J. McKay
Rok vydání:	2021
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Benzoin General Chemical Engineering General Physics and Astronomy General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences
Zdroj:	Journal of Photochemistry and Photobiology A: Chemistry. 421:113530
ISSN:	1010-6030
DOI:	10.1016/j.jphotochem.2021.113530
Popis:	Two novel photoremovable protecting groups in the benzoin class have been prepared and their photochemistry investigated. These polyaromatic benzoin photoremovable protecting groups have significantly improved molar extinction coefficients with absorptions that extend further towards the visible region of the spectrum and should not be hindered by a ‘inner filter’ effects, making them appealing for applications in sensitive environments. Our results show that these characteristics are not always translatable to photoresponsive efficacy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::86382bd3bb186544f85b04d0aa887d3f https://doi.org/10.1016/j.jphotochem.2021.113530 Zobrazit plný text záznamu Full Text from ScienceDirect