Synthesis and Characterization of the Homobimetallic [Bis(2-hydroxy-1-naphthaldehyde) oxaloyldihydrazonato]bisdioxomolybdenum(VI) Tetrahydrate Complex and its Reactivity towards Proton and Electron Donor Reagents

Autor:	Ram A. Lal, Arvind Kumar, Asim Pal, Syamal Adhikari, Alakananda N. Siva
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Tetrahydrate Proton Chemistry Molybdenum Stereochemistry Reagent Pyridine chemistry.chemical_element Electron donor Reactivity (chemistry) General Chemistry Medicinal chemistry
Zdroj:	Journal of Chemical Research. :122
ISSN:	1364-5560 0308-2342
DOI:	10.1039/a506810j
Popis:	The homobimetallic molybdenum(VI) complexes [(MoO 2 ) 2 (napoxlh)]·4H 2 O 1, [{(µ 2 -O)MoO 2 }MoO 2 (napoxl hH 2 )]·2L·4H 2 O, [L=pyridine (py) 2, 3-pic 3] and the molybdenum(V) complexes [MoO 2 (napoxlh)(sylsh) 2 ]·5H 2 O 4 and [Mo 2 (napoxlh)(inh) 2 (H 2 O) 2 ]·3H 2 O 5, (3-pic=3-picoline, sylshH 3 =salicyloylhydrazine and inhH 3 =isonicotinoylhydrazine) are synthesized from bis(2-hydroxy-1-naphthaldehyde) oxaloyldihydrazone (napoxlhH 4 ) and then characterized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8622eeae85485a3cdd8403674967296c https://doi.org/10.1039/a506810j Zobrazit plný text záznamu