Atom Transfer Radical Polymerization of Styrene and Acrylates: Effects of Catalyst, Ligand, Solvent, and Initiator

Autor:	M. W. Ullah, M. R. Alam, N. Haraguchi, M. A. Ali, Md. Mahiuddin, S. K. Ahamed
Rok vydání:	2021
Předmět:	Solvent chemistry.chemical_compound chemistry Atom-transfer radical-polymerization Ligand Polymer chemistry Styrene Catalysis
Zdroj:	Journal of Scientific Research. 13:999-1010
ISSN:	2070-0245 2070-0237
Popis:	Well-defined polystyrenes were successfully prepared by the CuX/(dN)bpy or CuX/ PMDETA catalyzed atom transfer radical polymerization of styrene using 1-phenylethyl bromide (1-PEBr) or benzyl bromide (BnBr) as initiators. We found that the CuX/PMDETA catalyzed ATRP of styrene proceeded faster than CuX/(dN)bpy catalyzed counterpart in bulk, diphenyl ether (DPE) and anisole. Using CuX/(dN)bpy catalyst, well-defined polystyrenes were obtained with good chain-end functionalities and low polydispersity (Mw/Mn
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::85def73f63e0079d1803e0f7066ec09d https://doi.org/10.3329/jsr.v13i3.53347 Zobrazit plný text záznamu Plný text ve formátu PDF