Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

Autor:	V. A. Navrotskii, T. P. Aleinikova
Rok vydání:	2014
Předmět:	General Chemical Engineering Radical Substrate (chemistry) General Chemistry Hydrogen atom abstraction Peroxide chemistry.chemical_compound chemistry Polymer chemistry Alkoxy group Organic chemistry Molecule Reactivity (chemistry) Selectivity
Zdroj:	Russian Journal of Applied Chemistry. 87:1890-1900
ISSN:	1608-3296 1070-4272
Popis:	α-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to 〉C=C〈 bonds. The selectivity of the synthesis of α-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate α-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of α-hydroxyalkyl peroxide esters and ethers were found.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::85d9f3ee337c61ba8be51dd1d982b01a https://doi.org/10.1134/s1070427214120167 Zobrazit plný text záznamu Full text from SpringerLink