Synthesis, characterization and visible-light photocatalytic properties of Bi2WO6 and Bi2W2O9 obtained by co-precipitation method
Autor: | S. Obregón Alfaro, A. Martínez-de la Cruz |
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Rok vydání: | 2010 |
Předmět: |
Thermogravimetric analysis
Diffuse reflectance infrared fourier transform Process Chemistry and Technology Analytical chemistry chemistry.chemical_element Catalysis Bismuth law.invention chemistry.chemical_compound chemistry Tungstate law Differential thermal analysis Rhodamine B Photocatalysis Calcination |
Zdroj: | Applied Catalysis A: General. 383:128-133 |
ISSN: | 0926-860X |
DOI: | 10.1016/j.apcata.2010.05.034 |
Popis: | The bismuth tungstates Bi 2 WO 6 and Bi 2 W 2 O 9 were prepared by co-precipitation method at different calcination temperatures. The oxides were characterized by different techniques such as simultaneous thermogravimetric and differential thermal analysis (TGA/DTA), X-ray powder diffraction (XRD), diffuse reflectance spectroscopy (DRS), nitrogen physisorption, and scanning electron microscopy (SEM). The photocatalytic activity of such bismuth tungstates was evaluated by degradation of rhodamine B under visible light irradiation. The degradation of the dye followed a first-order reaction with k ′ = 5.6 × 10 −3 min −1 and t 1/2 = 124 min for the best sample, which was Bi 2 W 2 O 9 prepared at 700 °C. |
Databáze: | OpenAIRE |
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