Synthesis and spectroscopic characterization of six new monosubstituted dithiocarbamate compounds containing organotellurium(IV) heterocycles: Single-crystal structures of C5H10TeI[S2CN(CH2CH3)2], C4H8TeI[S2CN(CH2CH2)2], C4H8OTeI[S2CN(CH2CH2)2] and C5H10TeI[S2CN(CH2CH2)2]
| Autor: | Patricia Martínez-Salas, María del Carmen Pérez-Redondo, Ave María Cotero-Villegas, Patricia García y García, Raymundo Cea Olivares, Herbert Höplf-Bachner, Marcela López-Cardoso |
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| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry Organic Chemistry chemistry.chemical_element Crystal structure Biochemistry Characterization (materials science) Inorganic Chemistry Crystallography chemistry Octahedron Materials Chemistry Physical and Theoretical Chemistry Tellurium Dithiocarbamate Single crystal Secondary bonding |
| Zdroj: | Journal of Organometallic Chemistry. 695:1246-1252 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2010.01.036 |
| Popis: | Six novel monosubstituted dithiocarbamate compounds containing organotellurium(IV) heterocycles, C4H8OTeI[S2CN(CH2CH3)2] (1), C5H10TeI[S2CN(CH2CH3)2] (2), C4H8TeI[S2CN(CH2CH2)2] (3), C8H8TeI[S2CN(CH2CH2)2] (4), C4H8OTeI[S2CN(CH2CH2)2] (5) and C5H10TeI[S2CN(CH2CH2)2] (6) were synthesized. The compounds were characterized by common spectroscopic methods; IR, EI-MS and multinuclear NMR (1H, 13C and 125Te). The structure of compounds 2, 3, 5 and 6 was uniequivocally established by single-crystal X-ray diffraction studies. Compounds 3, 4 and 5 exhibit dimeric arrangements achieved through secondary bonding (Te···S) and in the case of 2, an additional Te···S interaction resulted in the formation of a self-assembled chain. Furthermore, the geometrical arrangement displayed in the tellurium atoms of all the compounds corresponds to a distorted octahedron while the coordination mode for the dithiocarbamate ligands is considered anisobidentate in all cases. |
| Databáze: | OpenAIRE |
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