A ruthenium cis-dihydride with 2-phosphinophosphinine ligands catalyses the acceptorless dehydrogenation of benzyl alcohol

Autor:	Christian Luz, Elizabeth C. Trodden, Stephen M. Mansell, John M. Andresen, Robert J. Newland, Matthew P. Delve
Rok vydání:	2021
Předmět:	Inorganic Chemistry chemistry.chemical_compound 1h nmr spectroscopy chemistry Benzyl alcohol Ligand Benzyl benzoate Yield (chemistry) chemistry.chemical_element Dehydrogenation Medicinal chemistry Ruthenium
Zdroj:	Dalton Transactions. 50:13407-13411
ISSN:	1477-9234 1477-9226
Popis:	The first ruthenium dihydride complex featuring a phosphinine ligand cis-[Ru(H)2(2-PPh2-3-Me-6-SiMe3-PC5H2)2] was synthesised exclusively as the cis-isomer. When formed in situ from the reaction of cis-[Ru(Cl)2(2-PPh2-3-Me-6-SiMe3-PC5H2)2] with two equivalents of Na[BHEt3], as demonstrated by 31P and 1H NMR spectroscopy, the catalysed acceptorless dehydrogenation of benzyl alcohol was observed leading to benzyl benzoate in up to 70% yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::85bd0b6a116896c1356918244148eacc https://doi.org/10.1039/d1dt02508b Zobrazit plný text záznamu