Glass-Transition-, Melting-, and Decomposition Temperatures of Tailored Polyacrylates and Polymethacrylates: General Trends and Structure-Property Relationships
| Autor: | Mathieu Blanchot, Andrea Misske, Christopher Barner-Kowollik, Alexander P. Haehnel, Sylke Haremza, Friederike Fleischhaker |
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| Rok vydání: | 2014 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Organic Chemistry Thermal decomposition Context (language use) Polymer Condensed Matter Physics Homologous series chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Adhesive Polymer blend Physical and Theoretical Chemistry Glass transition Alkyl |
| Zdroj: | Macromolecular Chemistry and Physics. 215:1192-1200 |
| ISSN: | 1022-1352 |
| DOI: | 10.1002/macp.201400062 |
| Popis: | The glass-transition-, melting, and onset decomposition temperatures of a series of tailored polymethacrylates and polyacrylates are systematically investigated. Application fields of the investigated polymers include coatings, adhesives, textile, paper, cosmetics, electronics, lubricants, fuel additives, and oil-field or construction chemicals. The present study focuses on linear alkyl, branched alkyl, and amino, as well as ether polymethacrylates and polyacrylates. Novel polymers are introduced with branched C9, C13, C17, and C21 ester, Lupragen, or glycopyranoside ester groups. The thermal characteristics of the novel polymers are analyzed and placed into the context of the thermal data of known polymers fitting into the homologous series. General trends providing a comprehensive and concise overview of the determined thermal properties are derived. Structure-property relationships are established and a detailed physicochemical rationale is provided. The study may even allow for a rapid empirical estimation of thermal data of not yet assessed polymer systems. The thermal properties of a wide series of polyacrylates and polymethacrylates (among them completely novel structures) are systematically investigated for the first time. General trends are derived and structure-property relationships are established. The study provides a knowledge base, for industrial polymer applications, for a rapid empirical estimation of thermal polymer data, or for the tailored design of novel materials. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Databáze: | OpenAIRE |
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