Oxidation of 5-aminouracil with molecular oxygen in aqueous solution in the presence of copper(II) chloride

Autor:	Yu. I. Murinov, V. Yu. Mishinkin, S. A. Grabovskii, O. V. Akchurina, N. N. Kabal'nova
Rok vydání:	2017
Předmět:	Aqueous solution 010405 organic chemistry Ligand Inorganic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper 0104 chemical sciences Ion chemistry.chemical_compound chemistry Copper(II) chloride Molecular oxygen
Zdroj:	Russian Journal of General Chemistry. 87:1667-1674
ISSN:	1608-3350 1070-3632
Popis:	5-Aminouracil was found to form a six-coordinate copper(II) complex in aqueous solution and undergo oxidation to 5,5,6-trihydroxypyrimidine-2,4(1H,3H)-dione in the presence of molecular oxygen. A scheme was proposed for the fixation and activation of molecular oxygen on six-coordinate copper(II) complex with 5-aminouracil. The effect of the ligand structure on the rate of its oxidation with molecular oxygen in aqueous solution in the presence of copper(II) ions was shown.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::858d6601efdc0997aad72444ce8b0e6a https://doi.org/10.1134/s1070363217080047 Zobrazit plný text záznamu Plný text ve formátu PDF