Relationships between the efficiency of cyclohexane oxidation and the electrochemical parameters of the reaction solution

Autor:	Pawel Blonarz, Tomasz Paczeŝniak, Andriy Zaborovskyi, Jacques Muzart, Orest Fliunt, Roman Makitra, Yulia Kubaj, Alexander Pokutsa, Andrzej Sobkowiak, Ruslan Prystanskiy
Rok vydání:	2011
Předmět:	Cyclohexane Process Chemistry and Technology Oxalic acid Inorganic chemistry Relative permittivity Electrochemistry Catalysis Solvent chemistry.chemical_compound chemistry Yield (chemistry) Air atmosphere Physical and Theoretical Chemistry
Zdroj:	Journal of Molecular Catalysis A: Chemical. 347:15-21
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2011.07.003
Popis:	Vanadyl(IV)-acetylacetonate-catalyzed oxidation of cyclohexane with H2O2, at 40 °C under air atmosphere, has been studied in the presence of small quantities of oxalic acid. The process efficiency is increased by this additive and depends on the nature of the solvent (MeCN ≥ MeOH > Me2CO ≥ 2-PrOH > EtOH). The relationships between the results (conversion, yield) and the electrochemical characteristics of the reaction solution (relative permittivity, redox-potential) are highlighted and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::856fd932cf59e8766455850cb7842b2a https://doi.org/10.1016/j.molcata.2011.07.003 Zobrazit plný text záznamu Full Text from ScienceDirect