Influence of anion substitution on the crystal structure and color properties of copper-doped strontium hydroxyapatite
| Autor: | M.A. Pogosova, L.V. González |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Strontium
Materials science Diffuse reflectance infrared fourier transform Rietveld refinement Process Chemistry and Technology chemistry.chemical_element 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography symbols.namesake chemistry Materials Chemistry Ceramics and Composites symbols Hydroxyapatites 0210 nano-technology Colorimetry Raman spectroscopy Powder diffraction |
| Zdroj: | Ceramics International. 44:20140-20147 |
| ISSN: | 0272-8842 |
| DOI: | 10.1016/j.ceramint.2018.07.307 |
| Popis: | The copper-doped strontium hydroxyapatites with general formula Sr10(VO4)6-x(PO4)xO2CuyH2-y-δ (x = 0–6; y = 0–0.24) were synthesized through the solid state reaction technique. Synthesized materials were analyzed by the powder X-Ray diffraction (PXRD), Raman spectroscopy, diffuse reflectance spectroscopy, and colorimetry. A crystal structure of the materials obtained was characterized by the Rietveld refinement method (refined parameters included the unit cell dimensions, atomic positions, and position occupancies). All samples were shown to possess the hexagonal apatite structure (P63/m space group). It was established that the decrease of x changed the color of copper-doped samples which became more blue and intense. Influence of the anion substitution on crystal structure and color features of the copper-doped strontium hydroxyapatites was investigated for the first time. |
| Databáze: | OpenAIRE |
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