Novel catalysts for the carbonylation of methanol

Autor: Jonathan R. Dilworth, Michael James Baker, J. Glenn Sunley, John R. Miller, Nigel Wheatley
Rok vydání: 1995
Předmět:
Zdroj: Journal of the Chemical Society, Chemical Communications. :1579
ISSN: 0022-4936
Popis: Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl2(CO)2]–; the crystal structure of one procatalyst, [Rh(SC6H4PPh2)(CO)]2, is reported.
Databáze: OpenAIRE