Novel catalysts for the carbonylation of methanol
Autor: | Jonathan R. Dilworth, Michael James Baker, J. Glenn Sunley, John R. Miller, Nigel Wheatley |
---|---|
Rok vydání: | 1995 |
Předmět: | |
Zdroj: | Journal of the Chemical Society, Chemical Communications. :1579 |
ISSN: | 0022-4936 |
Popis: | Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl2(CO)2]–; the crystal structure of one procatalyst, [Rh(SC6H4PPh2)(CO)]2, is reported. |
Databáze: | OpenAIRE |
Externí odkaz: |