Halogen Substituted 1,3-Cyclohexanediones I. Reaction of 2,2-dichlorodimedone with bases

Autor: M. Verzele, Niceas Schamp
Rok vydání: 2010
Předmět:
Zdroj: Bulletin des Sociétés Chimiques Belges. 73:38-43
ISSN: 0037-9646
DOI: 10.1002/bscb.19640730106
Popis: The reaction of 2,2-dichlorodimedone with bases gives complex mixtures, but with silver oxide a straightforward reaction leads with high yield to 6,6-dichloro-4,4-dimethyl-5-oxohexanoic acid and/or to 4,4-dimethyl-5-chloroacetyl-2-tetrahydrofuranone. Identical reactions occur with 2,2-dichloro-1,3-cyclohexanedione.
Databáze: OpenAIRE