Halogen Substituted 1,3-Cyclohexanediones I. Reaction of 2,2-dichlorodimedone with bases
Autor: | M. Verzele, Niceas Schamp |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Bulletin des Sociétés Chimiques Belges. 73:38-43 |
ISSN: | 0037-9646 |
DOI: | 10.1002/bscb.19640730106 |
Popis: | The reaction of 2,2-dichlorodimedone with bases gives complex mixtures, but with silver oxide a straightforward reaction leads with high yield to 6,6-dichloro-4,4-dimethyl-5-oxohexanoic acid and/or to 4,4-dimethyl-5-chloroacetyl-2-tetrahydrofuranone. Identical reactions occur with 2,2-dichloro-1,3-cyclohexanedione. |
Databáze: | OpenAIRE |
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