Hydroalkylation of terminal aryl alkynes with alkyl diacyl peroxides
| Autor: | Liang Ge, Bo Qian, Kaki Raveendra Babu, You-Gui Li, Hongli Bao |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Aryl Radical Organic Chemistry chemistry.chemical_element Alkylation 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Photo catalysis chemistry.chemical_compound Nickel chemistry Reagent Drug Discovery Organic chemistry lipids (amino acids peptides and proteins) Olefin synthesis Alkyl |
| Zdroj: | Tetrahedron Letters. 57:5677-5680 |
| ISSN: | 0040-4039 |
| DOI: | 10.1016/j.tetlet.2016.11.020 |
| Popis: | A photo and nickel co-catalyzed hydroalkylation of terminal aryl alkynes enabled Z-preferred olefin synthesis has been developed under mild conditions. Alkyl diacyl peroxides were utilized as a new type of alkylation reagents and afforded Z-olefins as the major products in moderate to good yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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