The influence of sample rotation on the proton Zeeman relaxation behaviour of classically reorienting or tunnelling methyl groups

Autor: J. Smidt, D.J. Ligthelm, R.A. Wind
Rok vydání: 1981
Předmět:
Zdroj: Physica B+C. 104:397-402
ISSN: 0378-4363
DOI: 10.1016/0378-4363(81)90187-x
Popis: For the case the Zeeman relaxation is caused by classically reorienting or tunnelling methyl groups it is investigated how fast a sample has to be rotated to decouple Zeeman-and rotational polarization systems completely. It is found that rotating a sample with an angular velocity of 3 times the auto-Zeeman relaxation rate is sufficient to perform this.
Databáze: OpenAIRE