Iridium(IV) Chloride

Autor: Thomas R. B. Mitchell
Rok vydání: 2001
Předmět:
Zdroj: e-EROS Encyclopedia of Reagents for Organic Synthesis
DOI: 10.1002/047084289x.ri050
Popis: [10025-97-5] Cl4Ir (MW 334.02) InChI = 1S/4ClH.Ir/h4*1H;/q;;;;+4/p-4 InChIKey = CALMYRPSSNRCFD-UHFFFAOYSA-J (catalyst precursor for the stereoselective reduction of cyclohexanones1-3) Physical Data: decomposes on heating. Solubility: sol cold H2O, alcohol. Form Supplied in: dark brown, hygroscopic, amorphous mass. Pure iridium tetrachloride does not seem to have been made. Products sold as such contain water (about 10%) and may also contain some chloroiridic acid [H2IrCl6]. The manufacturer should state the iridium content. The ammonium salt [(NH4)2IrCl6], which can be obtained in a pure state, can be used instead.
Databáze: OpenAIRE