One-Electron Reduction of Molybdenum η2(4e)-Alkyne Complexes as a Pathway to the η2(3e) Vinyl Ligand

Autor:	Adrian C. Whitwood, Deborah C. Spinks, Sarah Baines, Andrew R. Chafen, Michael J. Cowley, Jason M. Lynam
Rok vydání:	2007
Předmět:	Inorganic Chemistry chemistry.chemical_classification chemistry Ligand Stereochemistry Molybdenum Organic Chemistry One-electron reduction Alkyne chemistry.chemical_element Physical and Theoretical Chemistry Medicinal chemistry
Zdroj:	Organometallics. 26:1093-1095
ISSN:	1520-6041 0276-7333
Popis:	Reaction of the molybdenum alkyne complex [Mo(P{OMe}3)2(η2{4e}-PhC2Ph)(η5-C5H5)][BF4] with K[Fe(CO)2(η5-C5H5)] results in the formation of the η2(3e)-vinyl complex and [Fe(CO)2(η5-C5H5)]2. A study ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8524cb6c16a12185e2b834b46f5f2f30 https://doi.org/10.1021/om060546f Zobrazit plný text záznamu