Tungsten 3p X-ray absorption spectrum of WF6

Autor:	Michel Tronc, Florence Guillot, Christine Dézarnaud-Dandine, F Bournel
Rok vydání:	1998
Předmět:	Valence (chemistry) Absorption spectroscopy Chemistry Ion yield X-ray Analytical chemistry General Physics and Astronomy Synchrotron radiation chemistry.chemical_element Physical and Theoretical Chemistry Tungsten Multiplet Spectral line
Zdroj:	Chemical Physics Letters. 286:317-320
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(98)00113-4
Popis:	The 3p (M3, M2) X-ray absorption spectrum of tungsten (2200–2600 eV) in gaseous WF6 has been obtained with synchrotron radiation using a total ion yield technique. Both the 3p3/2 and 3p1/2 spectra are dominated by the 3p→5d unresolved ligand-field split (t2g*+eg*) lines. The difference between the deconvoluted M3 and M2 doublet lines is related to multiplet effects due to the coupling between the 3p core and the 5d valence levels inducing differential intensity transfer between the t2g* and eg* components at the two edges.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8523eb98e77c3ec80d591cce5f931d7b https://doi.org/10.1016/s0009-2614(98)00113-4 Zobrazit plný text záznamu Full Text from ScienceDirect