Oxidatively induced insertion of an alkylidyne unit into the tungsten tris(pyrazolyl)borate cage

Autor:	Andreas Mayr, Samyoung Ahn
Rok vydání:	2000
Předmět:	Inorganic Chemistry Tris chemistry.chemical_compound chemistry Inorganic chemistry Materials Chemistry chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Tungsten Boron Cage Medicinal chemistry
Zdroj:	Inorganica Chimica Acta. :406-413
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(99)00580-0
Popis:	The oxidation of the complexes W(CHPh)(X)(BHPz 3 )(Br) (X=NCMe 3 , N -1-adamantyl, NC 6 H 2 -2,4,6-(CH 3 ) 3 , O) with Br 2 was investigated. The net outcome of the reactions is insertion of the benzylidyne unit into one of the WN bonds of the tungsten tris(pyrazolyl)borate cage to afford the complexes W{[C(Ph)C 3 H 3 N 2 BHPz 2 )](X)(Br 2 ). The crystal structures of two compounds of this type of complex with X= N -1-adamantyl and X=O have been determined by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8514a2d8dd53b1fa02a1b2ddfcb7339f https://doi.org/10.1016/s0020-1693(99)00580-0 Zobrazit plný text záznamu Full Text from ScienceDirect