A new polymer electrolyte for reversible photoresponsive ionic conduction

Autor:	Ryo Hirohashi, Koji Takazawa, Shoko Sato, Koji Ikeda, Norihisa Kobayashi
Rok vydání:	1995
Předmět:	chemistry.chemical_classification Spiropyran Chemistry General Chemical Engineering Inorganic chemistry Solid-state Polymer Electrolyte Photochemistry Photochromism chemistry.chemical_compound Electrochemistry Ionic conductivity Chelation Irradiation
Zdroj:	Electrochimica Acta. 40:2309-2311
ISSN:	0013-4686
DOI:	10.1016/0013-4686(95)00184-g
Popis:	This paper concerns photoinduced ionic conductivity response in the polymer electrolyte, which is synchronized with reversible photochromic chelation of spiropyran and a di-valent cation. The polymer having (methoxy)spiropyran groups, which is expected to show photochromic chelation with di-valent cations in the solid state upon uυ irradiation, was synthesized and complexed with ZnCl 2 . Reversible photoinduced ionic conductivity response was found in the resulting polymer electrolyte and was synchronized with reversible photochromic chelation. The photochromic chelation was revealed to decrease the carrier number in the polymer electrolyte and consequently to decrease the ionic conductivity. Further, the present photochromic chelation was easily suppressed by vis. illumination, resulting in the ionic conductivity being restored to the initial value.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::84ef7c00491510939819a0a38e110ded https://doi.org/10.1016/0013-4686(95)00184-g Zobrazit plný text záznamu Full Text from ScienceDirect