Reaction of 1-h-1-oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine or the potassium salt of 1-hydroxy-2,4,6,8-tetrakis(tert-butyl)-phenoxazin-10-yl radical with certain platinum metal derivatives

Autor: I. V. Karsanov, E. N. Ivakhnenko, A. I. Prokof'ev, V. S. Khandkarova, O. Yu. Okhlobystin, Vladimir I. Minkin, A. Z. Rubezhov, M. I. Kabachnik
Rok vydání: 1987
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:1707-1713
ISSN: 1573-9171
0568-5230
Popis: The reaction of 1-H-1-oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine or the K salt of 1-hydroxy-2,4,6,8-tetrakis(tert-butyl)phenoxazin-10-yl radical with platinum metal compounds forms paramagnetic complexes in which the unpaired electron is delocalized in the ligand. In the case of Pd and Pt allyl compounds the complexes are quite stable and can be isolated.
Databáze: OpenAIRE