Transformations of benzylvinylsilanes in presence of alkylation catalysts

Autor:	N. S. Nametkin, V. D. Oppengeim, E. Sh. Finkel'shtein, V. M. Vdovin
Rok vydání:	1964
Předmět:	Bicyclic molecule Chemistry Condensation General Chemistry Alkylation Chloride Medicinal chemistry Catalysis Solvent chemistry.chemical_compound Intramolecular force medicine Organic chemistry Benzene medicine.drug
Zdroj:	Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 13:429-434
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00844156
Popis:	1. An investigation was made of the behavior of benzylvinylsilanes of general formula CH2 = CHSi(R2)CH2\(\begin{array}{*{20}c} / \hfill & { - - - - } \hfill & \backslash \hfill \\ {\backslash \backslash } \hfill & { - - } \hfill & {//} \hfill \\ \end{array} \), (R = CH3, C2H5, Cl) in presence of various alkylation catalysts. 2. In presence of aluminum chloride benzyldimethylvinylsilane and benzyldichlorovinylsilane in benzene solution undergo cyclization by intramolecular alkylation. 3. In absence of solvent benzylvinylsilanes react in presence of aluminum chloride with formation of condensation products containing bicyclic groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::84ca23f3f7a6f8e0d205551bbdd64955 https://doi.org/10.1007/bf00844156 Zobrazit plný text záznamu Full text from SpringerLink