FT-Raman spectroscopic and density functional theory studies on ion preferential solvation and ion association of lithium tetrafluoroborate in 4-methoxymethyl ethylene carbonate-based mixed solvents
| Autor: | Xiangpeng Fang, Zhiming Zhou, Hongwei Qiao, Chang Chen, Jimei Li, Ye Tian, Wen Yao, Helin Luan, Xin Wang |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Hexamethyldisiloxane
Chemistry Organic Chemistry Inorganic chemistry Lithium tetrafluoroborate Ion-association Analytical Chemistry Inorganic Chemistry Contact angle chemistry.chemical_compound X-ray photoelectron spectroscopy Surface modification Fourier transform infrared spectroscopy Spectroscopy Ethylene carbonate |
| Zdroj: | Journal of Molecular Structure. 878:185-191 |
| ISSN: | 0022-2860 |
| Popis: | Using hexamethyldisiloxane (HMDSO) monomer, the magnetic nanoparticles (NPs) of nickel oxide (NiO) were modified by using an atmospheric room-temperature plasma fluidized bed (ARPFB). The plasma gas temperature of the ARPFB was not higher than 325 K, which was favorable for organic polymerization. The plasma optical emission spectrum (OES) of the gas mixture consisting of argon (Ar) and HMDSO was recorded by a UV-visible monochromator. The as-treated NPs were characterized by means of scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The results show that the assembling NPs were isolated greatly after modified by the organosilicon polymer. Moreover, this treatment process changed the wettability of the NPs from super-hydrophilicity to super-hydrophobicity, and the contact angle (CA) of water on the modified NPs surface exceeded 1508. Therefore, the ARPFB is a prospective technology for the NPs surface modification according to the different requirements. (C) 2007 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect