Molecular Recognition of the Dichiral Liquid Crystals Containing Fluorines

Autor:	Tamejiro Hiyama, Junko Umezawa, Miho Katoh, Hiroshi Matsutani, Yoichi Takanishi, Tetsuo Kusumoto, Atsushi Yoshizawa, Noriko Ise, Hideo Takezoe, Ken-ichi Sato
Rok vydání:	1999
Předmět:	Molecular aggregation Crystallography chemistry.chemical_compound Molecular recognition Liquid crystal Stereochemistry Chemistry Phase (matter) Enthalpy Ether Condensed Matter Physics Endothermic process Ferroelectricity
Zdroj:	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 330:227-234
ISSN:	1058-725X
Popis:	Novel dichiral liquid crystal compound 2-[4-((R)-2-fluorohexyloxy)phenyl]-5-[4-((S)-2-fluoro-2-methyldecanoyloxy)phenyl]-pyrimidine((R,S)-1) exhibits new optically isotropic phase (IsoX) with an endothermic transition enthalpy on cooling. In contrast, (S,S)-1 did not show the unusual transition. However, a 1:1 mixture of (S,S)-1 and (R,R)-1 exhibited IsoX phase. These results suggest that the appearance of IsoX phase is attributed to a chirality-dependent molecular recognition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::84c5a677a5a076be725ea9f2a2808504 https://doi.org/10.1080/10587259908025596 Zobrazit plný text záznamu