Substitution Reactions in a Diphosphirane Series: Evidence of 'CIS' Isomer Intermediate

Autor:	Jacques Berlan, Guita Etemad-Moghadam, Mostafa Rifqui, Max Koenig
Rok vydání:	1997
Předmět:	Substitution reaction Sonication Aryl Organic Chemistry Chlorine atom Gaseous hydrogen Photochemistry Chloride Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry polycyclic compounds Materials Chemistry medicine Diethyl ether Cis–trans isomerism medicine.drug
Zdroj:	Main Group Chemistry. 2:37-41
ISSN:	1745-1167 1024-1221
Popis:	In the diphosphirane series, the substitution of one aryl group (2,4,6-tri-tert-butyl‐phenyl) by a chlorine atom leading to the trans P‐chloro-diphosphirane via the cis isomer intermediate can be readily realized in chlorinated solvent under sonication or in the presence of gaseous hydrogen chloride in diethyl ether at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::84a9cdde4ad8aad265a30052bfe6f276 https://doi.org/10.1080/13583149712331338859 Zobrazit plný text záznamu