Synthese et etude des complexes [C5H4(CH2)3C5H4]Ti(C5H5)2 presentant un pont entre deux ligands cyclopentadienyles

Autor:	J. Tirouflet, A. Dormond, Ou-Khan
Rok vydání:	1976
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Organic Chemistry Materials Chemistry Titanocene dichloride Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 110:321-326
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)82491-2
Popis:	The complex (di-η 5 -C 5 H 4 CH 2 CH 2 CH 2 C 5 H 4 )Ti(η 1 -C 5 H 5 ) 2 (I) can be obtained unambiguously starting from the corresponding bridged titanocene dichloride. Attempts to synthesize the isomeric compounds (η 5 -C 5 H 5 ) 2 Ti(di-η 1 -C 5 H 4 -CH 2 CH 2 CH 2 C 5 H 4 ) (I′) by the action of a convenient bridged dianion on (C 5 H 5 ) 2 TiCl 2 afford several compounds, one of them is the complex I. The possibility of interconversion of these complexes by a fluctional process is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::847ea3ceef058576a6f18ca24285164c https://doi.org/10.1016/s0022-328x(00)82491-2 Zobrazit plný text záznamu