A highly twisting chiral qtz-d net built on a distorted tetrahedral node containing two types of helical substructure

Autor:	Ming-biao Luo, Zhen-wei Liao, Hai-xiao Huang, Feng Luo, Gong-ming Sun
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Diffraction Polymer Inorganic Chemistry Crystallography chemistry Group (periodic table) Materials Chemistry Net (polyhedron) Tetrahedron Substructure Hydrothermal synthesis Physical and Theoretical Chemistry Single crystal
Zdroj:	Inorganic Chemistry Communications. 14:1815-1818
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2011.08.016
Popis:	Herein, we present one chiral metal-organic polymer, namely Cd 2 (μ-H 2 O)(L) 2 (4,4′-bpy)( 1 , 4,4′-bpy = 4,4′-bipyridine H 2 L = 2-(4-carboxyphenoxy)benzoic acid). The single crystal X-ray diffraction shows that polymer 1 crystallizes in the chiral P6 5 22 space group, and the overall structural feature is the intriguing topological building of twisting chrial qtz-d net bulit on a higly rare distorted tetrahedral node, containing two types of helical substructure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::844b1eaac6335c82c94b17d5b06b3cf4 https://doi.org/10.1016/j.inoche.2011.08.016 Zobrazit plný text záznamu Full Text from ScienceDirect