Homolytic addition of benzyl bromide to unsaturated compounds in conditions of metal-complex initiation

Autor:	S. I. Gapusenko, S. V. Vitt, A. B. Terent'ev, T. T. Vasil'eva
Rok vydání:	1992
Předmět:	Chemistry General Chemistry Mass spectrometry Iron pentacarbonyl Adduct Homolysis Metal chemistry.chemical_compound Benzyl bromide visual_art Automotive Engineering Polymer chemistry visual_art.visual_art_medium Organic chemistry
Zdroj:	Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1841-1845
ISSN:	1573-9171 1063-5211
DOI:	10.1007/bf00863820
Popis:	Radical addition of benzyl bromide to unsaturated compounds containing substituents of a different polar nature, CH2=CHX (X=C4H9, SiMe3, CF3, CO2Me, CN, H), was conducted in the presence of the Fe(CO)5 + DMF (HMPA) system. Adducts were obtained and their structure was demonstrated by13C NMR and mass spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::843c51d5cca009ca3c140f912a36fb26 https://doi.org/10.1007/bf00863820 Zobrazit plný text záznamu Full text from SpringerLink