Composite zeolite hollow fiber membrane for the removal of nickel using forward osmosis
Autor: | Norfazilah Muhamad, Siti Nurfatin Nadhirah Mohd Makhtar, Mohamad Zahir Mohd Pauzi, Mohd Hafiz Dzarfan Othman, Khairul Hamimah Abas, Norfazliana Abdullah, Nizar Mu’ammar Mahpoz, Juhana Jaafar, Nor Akmal Fadil, Mukhlis A. Rahman |
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Rok vydání: | 2021 |
Předmět: |
Materials science
Process Chemistry and Technology Composite number Forward osmosis 02 engineering and technology 010501 environmental sciences 01 natural sciences Contact angle Membrane Adsorption 020401 chemical engineering Chemical engineering Hollow fiber membrane 0204 chemical engineering Fourier transform infrared spectroscopy Safety Risk Reliability and Quality Zeolite Waste Management and Disposal 0105 earth and related environmental sciences Biotechnology |
Zdroj: | Journal of Water Process Engineering. 40:101806 |
ISSN: | 2214-7144 |
Popis: | This work discusses the preparation, characterization, and feasibility test of composite zeolite hollow fiber membranes, with UV-curable resin as a secondary coating material, in removing Ni (II) using FO process. The preparation of the membrane started by depositing zeolite membrane onto alumina hollow fiber, followed by photopolymerization process once the outer layer was fully covered. Various characterization techniques were used on the composite membrane, namely field emission-scanning electron microscopy (FESEM), X-ray diffraction analysis, Fourier transform infrared (FTIR) spectroscopy, Brunauer–Emmett–Teller (BET) analysis, contact angle measurement, and performance tests using FO. The results show that the membranes enabled a reduction of reverse solute once incorporated with UV-curable resin. The lowest reverse solute flux obtained was 0.008 kg m−2 h−1, when pure water was flowed in the outer surface and 100,000 mg L−1 sodium chloride (NaCl) was used in the lumen. The UV-curable resin was unstable in the presence of Ni (II), which later formed complex ions. Adsorption of Ni (II) ions caused agglomeration of zeolite particles, causing membrane defects. |
Databáze: | OpenAIRE |
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