Structural Elucidation with Improved Dielectric and Magnetic Properties of Sol–Gel Synthesized Cr3+ Substituted M-Type Sr2+ Hexaferrites

Autor: Abdul Waheed, Muhammad Zahid, Aziz ur Rehman, Imran Sadiq, Ehsan Mazhar, Mohammed A. Assiri, Hasan M. Khan, Imran Khan, Nauman Usmani, Muhammad Imran
Rok vydání: 2021
Předmět:
Zdroj: Journal of Materials Engineering and Performance. 31:1530-1539
ISSN: 1544-1024
1059-9495
DOI: 10.1007/s11665-021-06263-5
Popis: Hexaferrites of Sr1-xCrxFe12O19 with x = (0.0, 0.1, 0.2, 0.3, 0.4, 0.5) were fabricated by citrate sol–gel technique. Characterization of grown samples such as structural and morphological analysis was performed by XRD and Scanning Electron Microscopy (SEM). Effect of Cr3+ incorporation on the electrical, structural and dielectric properties of Sr1-xCrxFe12O19 x = (0.0, 0.1, 0.2, 0.3, 0.4, 0.5) was reported. Confirmation of single phase M-type hexaferrite structure was carried out by the x-ray diffraction analysis. Lattice parameters have been reported to boost as the content of Cr3+ rises, which is due to the ionic size of the cation involved. SEM analysis indicates the decrease in grain size with the substitution of Cr3+. The dielectric constant and ac conductivity represent increasing behavior, while dielectric and tan loss indicate decreasing behavior with the increase in frequency and with Cr3+ content. The increasing decreasing trend of saturation magnetization was observed, and it is due to the different site occupancy of iron at different crystallographic sites. The coercivity values (6.64-6.72 KOe) of all samples were found to be in the range of M-type hexaferrites. These dielectric parameters values are appropriate for different applications in high-frequency devices such as modulators, phase shifters and also in longitudinal recording media.
Databáze: OpenAIRE
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