Polyhedral organoiridaazaborane chemistry. The preparation of the eleven-vertex nido compound [9-Cl-8-(η5-C5Me5)-nido-8,7-IrNHB9H10] and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy

Autor:	Karel Baše, Karl Nestor, John D. Kennedy, Mark Thornton-Pett, Bohumil Štíbr, Xavier L. R. Fontaine
Rok vydání:	1991
Předmět:	Crystallography Chemistry Stereochemistry X-ray crystallography chemistry.chemical_element Molecule General Chemistry Crystal structure Nuclear magnetic resonance spectroscopy Iridium Triclinic crystal system Spectroscopy Single crystal
Zdroj:	Collection of Czechoslovak Chemical Communications. 56:1607-1617
ISSN:	1212-6950 0010-0765
DOI:	10.1135/cccc19911607
Popis:	Reaction between nido-6-HNB9H11 (from[9-(MeNC)-arachno-6-HNB9H11] and [(η5-C5Me5).IrCl2]2 in the presence of N,N,N’,N’-tetramethylnaphthalene-1,8-diamine) gives [9-Cl-8-(η5-C5Me5)-nido-8,7-IrNHB9H10] as a yellow crystalline solid in 40% yield. Crystals are triclinic, space group P1, Z = 2, with a = 825.5(1), b = 986.4(2), c = 1 158.7(2) pm, α = 95.12(1), β = 91.00(1), γ = 111.90(1)°. The molecular structure is based on an open-faced nido {IrNB9} eleven-vertex polyhedron with the iridium and nitrogen atoms in adjacent positions in the open face. Nuclear magnetic single and multiple resonance spectroscopy assigns the cluster 11B and 1H resonances, and suggests strong electronic similarities to the sulphur-containing analogue [9-Cl-8-(η5-C5Me5)-nido-8,7-IrSB9H10].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::83b5dd6cd943fa95c6a2f96058bfc426 https://doi.org/10.1135/cccc19911607 Zobrazit plný text záznamu