The Synthesis of Dilithio-Trimethylenemethane by Thermal Rearrangement of Monolithio-2-Methylpropene

Autor: Richard J. Lagow, Maria M. Ludvig, Hajimu Kawa
Rok vydání: 1990
Předmět:
Zdroj: Synthetic Communications. 20:1657-1664
ISSN: 1532-2432
0039-7911
Popis: Unsolvated dilithio-trimethylenemethane has been prepared by the thermal rearrangement of the two structural isomers, 1-lithio-2-methylpropene and 3-lithio-2-methylpropene. This further extends the Kawa-Lagow modified Ziegler rearrangement to olefinic systems.
Databáze: OpenAIRE