Synthesis of isodrimenin from drim-8-en-7-one

Autor:	M. N. Coltsa, Pavel F. Vlad, Calin Deleanu, E. C. Gorincioi
Rok vydání:	2000
Předmět:	Thioketal chemistry.chemical_classification chemistry.chemical_compound chemistry Organic chemistry General Chemistry Lactone Raney nickel Nickel boride
Zdroj:	Russian Chemical Bulletin. 49:546-548
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf02494791
Popis:	A naturally occurring drimanic sesquiterpenic lactone, isodrimenin, was synthesized from drim-8-en-7-one (1). Compound1 was converted to the known 11,12-dihydroxydrim-8-en-7-one, which was oxidized with PCC to give 7-oxoisodrimenin. The thioketal of the latter compound was reduced with nickel boride or Raney nickel to give the target isodrimenin.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8338c68c51d33fece3407af07fd34494 https://doi.org/10.1007/bf02494791 Zobrazit plný text záznamu Full text from SpringerLink