Ring-chain tautomerism of vinylogs of 2(3)-amino derivatives of heterocyclic o-hydroxy aldehydes

Autor:	Alexander D. Dubonosov, Vladimir I. Minkin, A. Ya. Bushkov, Vladimir A. Bren, L. M. Sitkina
Rok vydání:	1984
Předmět:	chemistry.chemical_compound chemistry Chain (algebraic topology) Stereochemistry Organic Chemistry Substituent Amino derivatives Ring (chemistry) Spectroscopy Tautomer Cyclic form
Zdroj:	Chemistry of Heterocyclic Compounds. 20:951-957
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00506385
Popis:	Previously unknown vinylogs of 2(3)-aminomethylene-substituted benzo[b]thiophene-3-one, 1-methyloxindole, 1-methylindoxyl, benzo[b]furan-3-one, and indan-1,3-dione have been synthesized. Their tautomeric transformations have been studied by methods of UV, IR, and PMR spectroscopy. It has been shown that the introduction of a substituent into the β position of a dienic chain favors the appearance of the cyclic form.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::830fee84c9dc3b05572abca17bb17087 https://doi.org/10.1007/bf00506385 Zobrazit plný text záznamu Full text from SpringerLink