Polymers of diphenylamine-2-carboxylic acid: Synthesis, structure, and properties
| Autor: | T. N. Prudskova, G. P. Karpacheva, Galina N. Bondarenko, E. V. Veselova, S. Zh. Ozkan, I. S. Eremeev, G. A. Shandryuk |
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| Rok vydání: | 2013 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Polymers and Plastics chemistry.chemical_element Polymer Nitrogen Amorphous solid Ammonium hydroxide chemistry.chemical_compound chemistry Polymerization Polymer chemistry Materials Chemistry Ceramics and Composites Organic chemistry Diphenylamine-2-carboxylic acid |
| Zdroj: | Polymer Science Series B. 55:107-115 |
| ISSN: | 1555-6123 1560-0904 |
| Popis: | Polymers of diphenylamine-2-carboxylic acid are prepared by chemical oxidative polymerization in an aqueous solution of ammonium hydroxide. In accordance with the IR data, during the polymerization of diphenylamine-2-carboxylic acid in a solution of ammonium hydroxide, polymer-chain growth occurs via C-C joining into 2 and 4 positions of phenyl rings with respect to nitrogen. The distinctive feature of the polymer is the absence of quinodiimine units in its structure, even if the oxidizer is in excess. The resulting polymers are amorphous, electroactive, and thermally stable. |
| Databáze: | OpenAIRE |
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