Synthesis of atomically precise single-crystalline Ru2-based coordination polymers
| Autor: | David C. Powers, Gerard P. Van Trieste, Wen-Yang Gao |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Inert
chemistry.chemical_classification Coordination sphere Primary (chemistry) Materials science 010405 organic chemistry Systematic variation Polymer 010402 general chemistry Network topology Heterogeneous catalysis 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal Chemical engineering chemistry visual_art visual_art.visual_art_medium |
| Zdroj: | Dalton Transactions. 49:16077-16081 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/d0dt02233k |
| Popis: | Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal-organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru2 metallomonomers via labile Ag-N bonds provides access to a family of atomically precise single-crystalline Ru2-based coordination polymers with varied network topology and primary coordination sphere. |
| Databáze: | OpenAIRE |
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