Reactions of polyfluoro ketones with aromatic compounds

Autor:	B. R. Livshits, V. P. Palii, I. A. D'yachenko, N. P. Gambaryan
Rok vydání:	1967
Předmět:	chemistry.chemical_compound Hexafluoroacetone Trifluoromethyl Chemistry Group (periodic table) Condensation Organic chemistry Alcohol General Chemistry Intermediate product
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 16:591-595
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00905999
Popis:	1. By the condensation of hexafluoroacetone and pentafluoronitroacetone with aromatic hydrocarbons the corresponding substituted benzyl alcohols were synthesized. It was shown that in this reaction pentafluoronitroacetone is less active than hexafluoroacetone. 2. Inα-(difluoronitromethyl)-α-(trifluoromethyl)benzyl alcohols the difluoronitromethyl group is readily eliminated with formation of the corresponding ketones. 3. p-Methyl-α,α-bistrifluoromethylbenzyl alcohol is an intermediate product in the synthesis of hexafluoro-2,2 -di-p-tolylpropane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::82f5778adb7501fc6884f89ffc40259e https://doi.org/10.1007/bf00905999 Zobrazit plný text záznamu Full text from SpringerLink