Voltammetric Determination of Pd(II) Using 5-Hydroxyimino-4-imino-1,3-thiazolidin-2-one after a Thermal Activation of the Interaction

Autor: Lesya Oleksiv, Oleksandr Tymoshuk, T. I. Chaban, Oksana Labyk, Petro Rydchuk
Rok vydání: 2021
Předmět:
Zdroj: Chemistry & Chemical Technology. 15:324-329
ISSN: 1996-4196
DOI: 10.23939/chcht15.03.324
Popis: The interaction of Pd(II) with 5-hydroxyimino-4-imino-1,3-thiazolidin-2-one (HITO) was investigated over the pH range of 1.0–10.0. Optimal conditions for the voltammetric determination of Pd(II) were established. A new voltammetric method of Pd(II) determination by the peak of complex using NaCl as a supporting electrolyte at pH 2.0 was developed with the limit of detection 2.0∙10-7 M. The study of the method’s selectivity was presented in the work. The correctness of the method was confirmed by the analysis of model solutions and the real sample (resistor SP5-35B).
Databáze: OpenAIRE