Photodissociation of diphenyldiazomethane and energy relaxation in the diphenylcarbene fragment

Autor: M. J. McAuliffe, W.M. Hetherington, C. Dupuy, G.M. Korenowski, Kenneth B. Eisenthal
Rok vydání: 1981
Předmět:
Zdroj: Chemical Physics Letters. 77:272-274
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)80144-3
Popis: The dynamics of photodissociation of diphenyldiazomethane and energy relaxation in the diphenylcarbene fragment are investigated using picosecond laser methods. The equilibrium constant, free energy difference, and energy separation between the low-lying singlet and ground triplet states of the carbene are obtained.
Databáze: OpenAIRE