1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers
| Autor: | E. Yu. Fursova, V. I. Ovcharenko, Galina V. Romanenko, S. E. Tolstikov |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Ligand Bridging ligand Polymer 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Turn (biochemistry) chemistry.chemical_compound chemistry Transition metal Phase (matter) Pyridine Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Triazene |
| Zdroj: | Journal of Structural Chemistry. 61:707-711 |
| ISSN: | 1573-8779 0022-4766 |
| Popis: | 4,4′-(Triaz-1-ene-1,3-diyl)dipyridine (L) and the first transition metal complex with it are synthesized. It is found that the solid phase of isolated solvate [Cu(hfac)2L]·0.5MePh, where hfac is hexafluoroacetylacetonate, consists of polymer chains inside which L acts as a bridge, linking together Cu(hfac)2 moieties by N atoms of pyridine rings. The chains, in turn, are arranged into layers by H bonds. The result shows that L can be a bridging ligand in the synthesis of new coordination polymers. |
| Databáze: | OpenAIRE |
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