Temperature effects on the luminescence of Re(I) complexes: on the competitive relaxations of two electronic states

Autor:	J. Guerrero, I. Hsu, Ezequiel Wolcan, Guillermo Ferraudi, S. A. Moya, M.R. Feliz
Rok vydání:	1995
Předmět:	Chemistry General Engineering Halide State (functional analysis) Molecular physics Electronic states chemistry.chemical_compound Excited state Pyridine Emission spectrum Physical and Theoretical Chemistry Atomic physics Luminescence Ground state
Zdroj:	The Journal of Physical Chemistry. 99:4929-4934
ISSN:	1541-5740 0022-3654
Popis:	Emission spectra and luminescence rates of Re(CO){sub 3}L{sub 2}X (L{sub 2} = pyridine or bisquinoline derivatives, X = halide) have been measured in various media at temperatures between 298 and 77 K. The emission has been associated with parallel relaxations of two excited states: an intraligand state and a metal-to-ligand charge-transfer state. Rates of emission correlate with the excited state - ground state energy gap. Mechanisms mixing intraligand with charge-transfer states are proposed as means to explain the dependence of the emission rate on temperature. 41 refs., 6 figs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::82dfacf31059c4c851771f3c3baa9869 https://doi.org/10.1021/j100014a010 Zobrazit plný text záznamu