Reactions with Stilbenes and Related Derivatives. Part I. Reactions of 1, 2-Dihalogeno-1, 2-bis-(4-methoxyphenyl)ethanes with Alcohols

Autor:	Wadie Tadros, Moheb Sadek Ishak, Raouf Ramzi Tadros
Rok vydání:	1976
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Boiling Organic Chemistry Drug Discovery Organic chemistry Physical and Theoretical Chemistry Related derivatives Biochemistry Ethylene glycol Catalysis
Zdroj:	Helvetica Chimica Acta. 59:1925-1930
ISSN:	1522-2675 0018-019X
DOI:	10.1002/hlca.19760590603
Popis:	The reaction of 1, 2-dibromo-1, 2-bis(4-methoxyphenyl)ethane with alcohols was associated with rearrangement to give the corresponding bis(4-methoxyphenyl)acetals. In boiling ethylene glycol 4,4′-dimethoxy-deoxybenzoin was also obtained due to an aldehyde-ketone rearrangement. 4,4′-Dimethoxybenzophenone was also formed being apparently derived from the acetals. The mechanism of formation of the acetals has been discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::82d7a44abf84c3184fc08d71a79652a4 https://doi.org/10.1002/hlca.19760590603 Zobrazit plný text záznamu Plný text