Microcontact Printing of Uniform Nanoparticle Arrays

Autor: Ronald P. Andres, Venugopal Santhanam
Rok vydání: 2003
Předmět:
Zdroj: Nano Letters. 4:41-44
ISSN: 1530-6992
1530-6984
DOI: 10.1021/nl034851r
Popis: Uniform, close-packed monolayer and bilayer arrays of alkanethiol-coated gold nanoparticles have been used as “ink” for microcontact printing (μCP) following the technique of Xia and Whitesides (see Xia, Y.; Whitesides, G. M. Polym. Mater. Sci. Eng. 1997, 77, 596). The process is accomplished in two steps. First, a uniform monolayer of the nanoparticles is self-assembled on a water surface and is transferred intact to a patterned poly(dimethylsiloxane) (PDMS) stamp pad by the Langmuir−Schaefer (LS) method. In the case of multilayer printing, this “inking” step is repeated as many times as desired. Because multilayer arrays are assembled on the stamp pad layer-by-layer, adjacent layers may be made up of the same or different particles. The nanoparticles are transferred to a solid substrate by conformal contact of the stamp pad and the substrate. The technique has been used to print patterned monolayer and bilayer arrays on both hydrophobic and hydrophilic substrates. The quality of the transferred arrays h...
Databáze: OpenAIRE