Coordination modification and sorption properties of mesoporous chromium(III) terephthalate

Autor:	P. V. Burlak, Vladimir P. Fedin, Konstantin A. Kovalenko, Anastasia M. Cheplakova
Rok vydání:	2015
Předmět:	Coordination sphere Pyrazine Ligand Materials Science (miscellaneous) Inorganic chemistry chemistry.chemical_element Sorption Nitrogen Inorganic Chemistry chemistry.chemical_compound Chromium Adsorption chemistry Physical and Theoretical Chemistry Mesoporous material
Zdroj:	Russian Journal of Inorganic Chemistry. 60:790-794
ISSN:	1531-8613 0036-0236
Popis:	Mesoporous chromium(III) terephthalate MIL-101 was modified with pyrazine, 1,4-diaza[2.2.2]bicyclooctane, and 4,4′-bipyridyl by the replacement of aqua ligands in chromium coordination sphere by coordinated organic ligands. Effect of ligand size on the sorption characteristics of the modified frameworks toward nitrogen and carbon dioxide was studied. It was shown that bulky 4,4′-bipyridyl can block the mesocavities of metal-organic framework. It was shown that basic centers in the modified frameworks increase adsorption heat of carbon dioxide by about 1.5 times.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::82bdb8677f84d90fb12e514a13a7ed97 https://doi.org/10.1134/s0036023615070086 Zobrazit plný text záznamu Full text from SpringerLink