Study of the addition of diazoles to vinylsilanes
| Autor: | P. A. Storozhenko, D. A. Cheshkov, A. M. Abramkin, V. D. Sheludyakov, N. E. Kuz’mina |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Indazole
chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy Pyrazole Medicinal chemistry Silane chemistry.chemical_compound chemistry Reagent Organic chemistry Lithium Two-dimensional nuclear magnetic resonance spectroscopy Heteronuclear single quantum coherence spectroscopy |
| Zdroj: | Russian Journal of General Chemistry. 81:2459-2467 |
| ISSN: | 1608-3350 1070-3632 |
| Popis: | The reaction of trimethoxy(vinyl)silane with diazoles in the presence of metal lithium was studied. The structure of the reaction products was assigned by NMR spectroscopy (1H, 13C, 29Si, COSY, NOESY, HMBC, and HSQC). An explanation for the different reactivities of reagents (aliphatic amines, diazoles, allylalkylsilanes, vinylalkylsilanes, and vinylalkoxysilanes) was provided. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|