Infrared Absorption Spectra of Solid Solutions: Cluster Formation of Nitrate Ions in Alkali Halides
| Autor: | J. van der Elsken, S. G. Kroon |
|---|---|
| Rok vydání: | 1964 |
| Předmět: |
Chemistry
Inorganic chemistry Analytical chemistry General Physics and Astronomy Infrared spectroscopy Halide Interaction energy Alkali metal Ion chemistry.chemical_compound Nitrate Physics::Space Physics Cluster (physics) Physical and Theoretical Chemistry Physics::Atmospheric and Oceanic Physics Solid solution |
| Zdroj: | The Journal of Chemical Physics. 41:3451-3452 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.1725747 |
| Popis: | Satellite bands appearing in spectra of dilute solid solutions of nitrate ions in alkali halide crystals have been identified as arising from clusters of two or more nitrate ions. The dependence of the number of clusters on the concentration has been determined. Out of the discrepancy between this dependence and the theoretically expected dependence an interaction energy can be estimated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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