Deracemization of 2-alkylcyclohexanones utilizing host-guest molecular association with optically active host compounds in basic suspension media

Autor:	Etsuko Okuyama, Miwa Nagaku, Tetsuto Tsunoda, Hiroto Kaku
Rok vydání:	1997
Předmět:	genetic structures Chemistry Yield (chemistry) Organic Chemistry Drug Discovery Solid-state Organic chemistry Optically active Enantiomeric excess Biochemistry eye diseases Suspension (chemistry)
Zdroj:	Tetrahedron Letters. 38:7759-7760
ISSN:	0040-4039
Popis:	Based on host-guest inclusion complexation in the solid state, α-substituted cyclohexanones 2a-c were deracemized using optically active host compounds in alkaline conditions to optically active 2 in excellent chemical yield with high enantiomeric excess.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::829e28930ab77913a2ff4804f274d9e5 https://doi.org/10.1016/s0040-4039(97)10071-5 Zobrazit plný text záznamu Full Text from ScienceDirect