Reaction of bulky organosilicon compounds with CS2: Cleavage and rearrangement reactions of 1,2-epoxides

Autor:	Mahsa Ebrahiminia, Khatereh Ghorbanpour, Kazem D. Safa
Rok vydání:	2014
Předmět:	Tris Carbon disulfide Trimethylsilyl Organic Chemistry Carbon-13 NMR Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Structural isomer Organic chemistry Methyllithium Physical and Theoretical Chemistry Organosulfur compounds Organosilicon
Zdroj:	Journal of Organometallic Chemistry. 762:29-33
ISSN:	0022-328X
Popis:	The reaction of tris(trimethylsilyl)methyllithium, (Me 3 Si) 3 CLi, and carbon disulfide with various epoxides have been studied. By an unusual rearrangement hydroxy-mercaptobis-(trimethylsilyl)-thiones have been synthesized in good yields. Unexpectedly, in the case of 2-phenyloxirane two structural isomers ( 2g ) and ( 2h ) have been formed which was confirmed by IR, 1 H and 13 C NMR spectroscopy. Moreover, the reaction of (PhMe 2 Si) 3 CLi and (Me 3 Si) 3 CLi with CS 2 in the presence of epoxides has been compared.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8293d03dab60e6569a0f928afeca1a87 https://doi.org/10.1016/j.jorganchem.2014.02.019 Zobrazit plný text záznamu Full Text from ScienceDirect